Publications
2025
230. Catalytic Dioxygen Activation Using a Diketopiperazine and a Manganese Catalyst for Selective C(sp3)–H Oxidation
Kyriaki Gennaiou, Arnau Call, Nikos Siakavaras, Miquel Costas, Alexandros L. Zografos
JACS Au 2025, ASAP [doi]
229. Characterization and targeting of chemoresistant triple-negative breast cancer subtypes using amino-pyridine compounds
Santiago Ruiz-Martínez, Xavi Ribas, Miquel Costas, Göran Landberg, Teresa Puig
Biochim. Biophys. Acta - Mol. Basis Dis. 2025, 1871, 167899 [doi]
228. Iron-Catalyzed Intermolecular N–H Insertion Using Acceptor–Acceptor Carbenes Derived from Iodonium Ylides
Àlex Díaz-Jiménez, Nil Insa-Carreras, Anna Roglans, Anna Pla-Quintana, Miquel Costas
Org. Lett. 2025, 27, 7804-7809 [doi]
227. Shaping of a Reactive Manganese Catalyst Enables Access to Polyfunctionalized Cyclohexanes via Enantioselective C(sp3)─H Bond Oxidation of 1,3-meso Diethers
Andrea Palone, Arnau Call, Aleria Garcia-Roca, Josep M. Luis, Matthew S. Sigman, Massimo Bietti, Cristina Nevado, Miquel Costas
Angew. Chem. Int. Ed. 2025, 64, e202507755 [doi]
226. Manganese-Catalyzed Enantioselective Dearomative Epoxidation of Naphthalenes with Aqueous Hydrogen Peroxide
Najoua Choukairi Afailal, Siu-Chung Chan, Miquel Costas
Angew. Chem. Int. Ed. 2025, 64, e202504356 [doi]
225. Alkane recognition enhanced by solvophobic interactions enables site-selective aliphatic C-H oxidation
Marco Galeotti, Laia Vicens, Miquel Costas
Chem. 2025, 11, e202507755 [doi]
224. Unveiling the Catalytic Activity of Nickel(II) Complexes of Pentadentate Ligands in Aromatic Oxidations
Anjana Rajeev, Sethuraman Muthuramalingam, Visvesvarar Pitchai Murugan, Miquel Costas, Prabha Vadivelu, Muniyandi Sankaralingam
ChemCatChem. 2025, 17, e202401645 [doi]
223. Understanding Catalytic Enantioselective C–H Bond Oxidation at Nonactivated Methylenes Through Predictive Statistical Modeling Analysis
Arnau Call, Andrea Palone, Jordan P. Liles, Natalie P. Romer, Jacquelyne A. Read, Josep M. Luis, Matthew S. Sigman, Massimo Bietti, Miquel Costas
ACS Catal. 2025, 15, 2110-2123 [doi]
222. Enzymatic and Bio-Inspired Enantioselective Oxidation of Non-Activated C(sp3)–H Bonds
Andrea Palone, Massimo Bietti, Miquel Costas
Synthesis 2025, 57, 1280-1294 [doi]
2024
222. Intramolecular C–H Oxidation in Iron(V)-oxo-carboxylato Species Relevant in the γ-Lactonization of Alkyl Carboxylic Acids
Andrea Álvarez-Núñez, Rudraditya Sarkar, Valeria Dantignana, Jin Xiong, Yisong Guo, Josep M. Luis, Miquel Costas, Anna Company
ACS Catal. 2024, 14, 14183-14194 [doi]
221. Activation of hydrogen peroxide with biologically inspired non-heme iron and manganese catalysts: From simple molecular complexes to modification of the second coordination sphere
Laia Vicens, Miquel Costas
Adv. Inorg. Chem. 2024, 84, 1-19 [doi]
220. Proton-triggered chemoselective halogenation of aliphatic C–H bonds with nonheme FeIV-oxo complexes
Neus Pagès-Vilà, Ilaria Gamba, Martin Clémancey, Jean-Marc Latour, Anna Company, Miquel Costas
J. Inorg. Biochem. 2024, 259, 112643 [doi]
219. tert-Butyl as a Functional Group: Non-Directed Catalytic Hydroxylation of Sterically Congested Primary C−H Bonds
Siu-Chung Chan, Andrea Palone, Massimo Bietti, Miquel Costas
Angew. Chem. Int. Ed. 2024, 63, e202402858 [doi]
218. Catalyst and Medium Control over Rebound Pathways in Manganese-Catalyzed Methylenic C–H Bond Oxidation
Marco Galeotti, Massimo Bietti, Miquel Costas
J. Am. Chem. Soc. 2024, 146, 8904-8914 [doi]
217. Proximity Effects on the Reactivity of a Nonheme Iron (IV) Oxo Complex in C-H Oxidation
Alessandro Fagnano, Federico Frateloreto, Roberta Paoloni, Carla Sappino, Osvaldo Lanzalunga, Miquel Costas, Stefano Di Stefano, Giorgio Olivo
Angew. Chem. Int. Ed. 2024, 63, e202401694 [doi]
216. Dearomative syn-Dihydroxylation of Naphthalenes with a Biomimetic Iron Catalyst
Najoua Choukairi Afailal, Margarida Borrell, Marco Cianfanelli, Miquel Costas
J. Am. Chem. Soc. 2024, 146, 240-249 [doi]
215. Synthesis, Structure and Reactivity of a Mononuclear N,N,O-Bound Fe(II) α-Keto-Acid Complex
Emily Monkcom, Laura Gómez, Martin Lutz, Shengfa Ye, Eckhard Bill, Miquel Costas, Robertus J. Klein Gebbink
Chem. Eur. J. 2024, 30, e202302710 [doi]
2023
214. Asymmetric C-H Oxidation with Biologically Inspired Manganese and Iron Catalysts
Laia Vicens, Andrea Palone, Miquel Costas
in Science of Synthesis: Base-Metal Catalysis 2 (Thieme, 2023) [doi]
213. Highly Selective C(sp3)-H Bond Oxygenation at Remote Methylenic Sites Enabled by Polarity Enhancement
Sergio Sisti, Marco Galeotti, Filippo Scarchilli, Michela Salamone, Miquel Costas, Massimo Bietti
J. Am. Chem. Soc. 2023, 145, 22086-22096 [doi]
212. Highly Enantioselective Catalytic Lactonization at Nonactivated Primary and Secondary γ-C–H Bonds
Arnau Call, Giorgio Capocasa, Andrea Palone, Laia Vicens, Eric Aparicio, Najoua Choukairi Afailal, Nikos Siakavaras, Maria Eugènia López Saló, Massimo Bietti, Miquel Costas
J. Am. Chem. Soc. 2023, 145, 15742-18103 [doi]
211. C–H Bonds as Functional Groups: Simultaneous Generation of Multiple Stereocenters by Enantioselective Hydroxylation at Unactivated Tertiary C–H Bonds
Andrea Palone, Guillem Casadevall, Sergi Ruiz-Barragan, Arnau Call, Sílvia Osuna, Massimo Bietti, Miquel Costas
J. Am. Chem. Soc. 2023, 145, 15742-15753 [doi]
210. Reversible Deactivation of Manganese Catalysts in Alkene Oxidation and H2O2 Disproportionation
Johann B. Kasper, Laia Vicens, C. Maurits de Roo, Ronald Hage, Miquel Costas, and Wesley R. Browne
ACS Catal. 2023, 13, 6403-6415 [doi]
209. Site-selective methylene C–H oxidation of an alkyl diamine enabled by supramolecular recognition using a bioinspired manganese catalyst
Arnau Vicens, Laia Vicens, Giorgio Olivo, Osvaldo Lanzalunga, Stefano Di Stefano, Miquel Costas
Faraday Discuss. 2023, 244, 51-61 [doi]
208. An investigation of steric influence on the reactivity of FeV(O)(OH) tautomers in stereospecific C–H hydroxylation
Mainak Mitra, Alexander Brinkmeier, Yong Li, Margarida Borrell, Arnau Call, Julio Lloret-Fillol, Michael G. Richmond, Miquel Costas, Ebbe Nordlander
Dalton Trans. 2023, 52, 3596-3609 [doi]
207. A Common Active Intermediate in the Oxidation of Alkenes, Alcohols and Alkanes with H2O2 and a Mn(II)/Pyridin-2-Carboxylato Catalys
Johann B. Kasper, Pattama Saisaha, Maurits de Roo, Mitchell J. Groen, Laia Vicens, Margarida Borrell, Johannes W. de Boer, Ronald Hage, Miquel Costas, Wesley R. Browne
ChemCatChem 2023, 15, e202201072 [doi]
206. Characterization of a Ferryl Flip in Electronically Tuned Nonheme Complexes. Consequences in Hydrogen Atom Transfer Reactivity
Valeria Dantignana, M. Carmen Pérez-Segura, Pau Besalú-Sala, Estefanía Delgado-Pinar, Álvaro Martínez-Camarena, Joan Serrano-Plana, Andrea Álvarez-Núñez, Carmen E. Castillo, Enrique García-España, Josep M. Luis, Manuel G. Basallote, Miquel Costas, Anna Company
Angew. Chem. Int. Ed. 2023, 62, e202211361 [doi]
2022
205. Carboxylic Acid Directed γ-Lactonization of Unactivated Primary C–H Bonds Catalyzed by Mn Complexes: Application to Stereoselective Natural Product Diversification
Arnau Call, Marco Cianfanelli, Pau Besalú-Sala, Giorgio Olivo, Andrea Palone, Laia Vicens, Xavi Ribas, Josep M. Luis, Massimo Bietti, and Miquel Costas
J. Am. Chem. Soc. 2022, 144, 19542-19558 [doi]
204. Resolving Oxygenation Pathways in Manganese-Catalyzed C(sp3)–H Functionalization via Radical and Cationic Intermediate
Marco Galeotti, Laia Vicens, Michela Salamone, Miquel Costas, Massimo Bietti
J. Am. Chem. Soc. 2022, 144, 7391-7401 [doi]
203. 38P New tetraamine compounds targeting BCSCs from chemoresistant basal-like TNBC subtype
Aitor Sevillano Chapartegui, Mònica Rodríguez, Miquel Costas, Xavi Ribas, Santiago Ruiz-Martínez, Teresa Puig
Ann. Oncol. 2022, 33, S17 [doi]
202. Remote Amino Acid Recognition Enables Effective Hydrogen Peroxide Activation at a Manganese Oxidation Catalyst
Laia Vicens, Giorgio Olivo, Miquel Costas
Angew. Chem. Int. Ed. 2022, 61, e202114932 [doi]
201. Oxidative C−F Cleavage in Metalloenzymes and Model Compounds
Miquel Costas, Anna Company
Eur. J. Inorg. Chem. 2022, e202100754 [doi]
2021
200. Site and Enantioselective Aliphatic C−H Oxidation with Bioinspired Chiral Complexes
Miquel Costas
Chem. Rec. 2021, 21, 4000-4014 [doi]
199. Aromatic C−H Hydroxylation Reactions with Hydrogen Peroxide Catalyzed by Bulky Manganese Complexes
Eduard Masferrer-Rius, Margarida Borrell, Martin Lutz, Miquel Costas, Robertus J. M. Klein Gebbink
Adv. Synth. Catal. 2021, 363, 3787-3795 [doi]
198. Electrocatalytic Water Oxidation with α-[Fe(mcp)(OTf)2] and Analogues
Silvia D’Agostini, Konstantin G. Kottrup, Carla Casadevall, Ilaria Gamba, Valeria Dantignana, Alberto Bucci, Miquel Costas, Julio Lloret-Fillol, and Dennis G.H. Hetterscheid
ACS Catal. 2021, 11, 2583-2595 [doi]
197. Remote Oxidation of Aliphatic C–H Bonds with Biologically Inspired Catalysts
Miquel Costas
in Remote C–H Bond Functionalizations: Methods and Strategies in Organic Synthesis (Wiley, 2021) [doi]
196. Spin State Tunes Oxygen Atom Transfer towards FeIVO Formation in FeII Complexes
Carmen E. Castillo, Ilaria Gamba, Laia Vicens, Martin Clémancey, Jean-Marc Latour, Miquel Costas, Manuel G. Basallote
Chem. Eur. J. 2021, 27, 4946-4954 [doi]
195. General Access to Modified α-Amino Acids by Bioinspired Stereoselective γ-C−H Bond Lactonization
Laia Vicens, Massimo Bietti, Miquel Costas
Angew. Chem. Int. Ed. 2021, 60, 4740-4746 [doi]
194. Morbidly obese subjects show increased serum sulfide in proportion to fat mass
Ferran Comas, Jèssica Latorre, Francisco Ortega, María Arnoriaga Rodríguez, Aina Lluch, Mònica Sabater, Ferran Rius, Xavi Ribas, Miquel Costas, Wifredo Ricart, Albert Lecube, José Manuel Fernández-Real,José María Moreno-Navarrete
Int. J. Obes. 2021, 45, 415-426 [doi]
2020
193. Iron-Catalyzed Intermolecular Functionalization of Non-Activated Aliphatic C−H Bonds via Carbene Transfer
Mònica Rodríguez, Gemma Font, Joel Nadal-Moradell, Alberto Hernán-Gómez, Miquel Costas
Adv. Synth. Catal. 2020, 362, 5116-512 [doi]
192. Mechanistic Insights into the ortho-Defluorination-Hydroxylation of 2-Halophenolates Promoted by a Bis(μ-oxo)dicopper(III) Complex
Pau Besalú-Sala, Carla Magallón, Miquel Costas, Anna Company, Josep M. Luis
Inorg. Chem. 2020, 59, 17018-17027 [doi]
191. Catalytic O2 activation with synthetic models of α-ketoglutarate dependent oxygenases
Brenda N. Sánchez-Eguía, Joan Serrano-Plana, Anna Company, Miquel Costas
Chem. Commun. 2020, 45, 415-426 [doi]
190. Complete Dynamic Reconstruction of C60, C70, and (C59N)2 Encapsulation into an Adaptable Supramolecular Nanocapsule
Cristina García-Simón, Cédric Colomban, Yarkin Aybars Çetin, Ana Gimeno, Míriam Pujals, Ernest Ubasart, Carles Fuertes-Espinosa, Karam Asad, Nikos Chronakis, Miquel Costas, Jesús Jiménez-Barbero, Ferran Feixas, Xavi Ribas
J. Am. Chem. Soc. 2020, 142, 16051-16063 [doi]
189. Rational Design of Bioinspired Catalysts for Selective Oxidations
Laia Vicens, Giorgio Olivo, Miquel Costas
ACS Catal. 2020, 10, 8611-8631 [doi]
188. Catalytic Oxidation of Primary C–H Bonds in Alkanes with Bioinspired Catalysts
Valeria Dantignana, Anna Company, Miquel Costas
Chimia 2020, 74, 470-477 [doi]
187. Predictable Selectivity in Remote C−H Oxidation of Steroids: Analysis of Substrate Binding Mode
Giorgio Olivo, Giorgio Capocasa, Barbara Ticconi, Osvaldo Lanzalunga, Stefano Di Stefano, Miquel Costas
Angew. Chem. Int. Ed. 2020, 59, 12703-12708 [doi]
186. Site-Selective and Product Chemoselective Aliphatic C–H Bond Hydroxylation of Polyhydroxylated Substrates
Margarida Borrell, Sergio Gil-Caballero, Massimo Bietti, Miquel Costas
Angew. Chem. Int. Ed. 2020, 59, 12703-12708 [doi]
185. Oxoiron(V) Complexes of Relevance in Oxidation Catalysis of Organic Substrates
Valeria Dantignana, Anna Company, Miquel Costas
Isr. J. Chem. 2020, 60, 1004-1018 [doi]
184. Enantioselective C–H Lactonization of Unactivated Methylenes Directed by Carboxylic Acids
Marco Cianfanelli, Giorgio Olivo, Michela Milan, Robertus J. M. Klein Gebbink, Xavi Ribas, Massimo Bietti, Miquel Costas
J. Am. Chem. Soc.​ 2020, 142, 1584-1593 [doi]
183. Supramolecular Fullerene Sponges as Catalytic Masks for Regioselective Functionalization of C60
Carles Fuertes-Espinosa, Cristina García-Simón, Míriam Pujals, Marc Garcia-Borràs, Laura Gómez, Teodor Parella, Judit Juanhuix, Inhar Imaz, Daniel Maspoch, Miquel Costas, Xavi Ribas
Chem. 2020, 6, 169-186 [doi]
2019
182. Asymmetric Epoxidation Catalyzed by Biologically Inspired Non-heme Iron Catalysts and Hydrogen Peroxide
Laia Vicens, Miquel Costas
in Frontiers of Green Catalytic Selective Oxidations (Springer, 2019) [doi]
181. Z = 25, manganeso, Mn. El metal del centro generador de O2 en la fotosíntesis
Miquel Costas
An. Quim. 2019, 115, 87 [doi]
180. Spectroscopic and Reactivity Comparisons between Nonheme Oxoiron(IV) and Oxoiron(V) Species Bearing the Same Ancillary Ligand
Valeria Dantignana, Joan Serrano-Plana, Apparao Draksharapu, Carla Magallón, Saikat Banerjee, Ruixi Fan, Ilaria Gamba, Yisong Guo, Lawrence Que Jr., Miquel Costas, Anna Company
J. Am. Chem. Soc. 2019, 141, 15078-15091 [doi]
179. Octahedral iron(IV)–tosylimido complexes exhibiting single electron-oxidation reactivity
Gerard Sabenya, Ilaria Gamba, Laura Gómez, Martin Clémancey, Jonathan R. Frisch, Eric J. Klinker, Geneviève Blondin, Stéphane Torelli, Lawrence Que Jr, Vlad Martin-Diaconescu, Jean-Marc Latour, Julio Lloret-Fillol, Miquel Costas
Chem. Sci. 2019, 10, 9513-9529 [doi]
178. Chemoselectivity in the Oxidation of Cycloalkenes with a Non-Heme Iron(IV)-Oxo-Chloride Complex: Epoxidation vs. Hydroxylation Selectivity
Thibault Terencio, Erik Andris, Ilaria Gamba, Martin Srnec, Miquel Costas, Jana Roithová
J. Am. Soc. Mass Spectrom. 2019, 30, 1923-18¡933 [doi]
177. Electrophilic Iron Catalyst Paired with a Lithium Cation Enables Selective Functionalization of Non-Activated Aliphatic C−H Bonds via Metallocarbene Intermediates
Alberto Hernán-Gómez, Mònica Rodríguez, Teodor Parella, Miquel Costas
Angew. Chem. Int. Ed.​ 2019, 58, 13904-13911 [doi]
176. Green Oxidative Synthesis of Epoxides
Miquel Costas
in Green Oxidation in Organic Synthesis (Wiley, 2019) [doi]
175. Hydrogen sulfide impacts on inflammation-induced adipocyte dysfunction
Ferran Comas, Jèssica Latorre, Olaf Cussó, Francisco Ortega, Aina Lluch, Mònica Sabater, Anna Castells-Nobau, Wifredo Ricard, Xavier Ribas, Miquel Costas, José Manuel Fernández-Real, José María Moreno-Navarrete
Food Chem. Toxicol. 2019, 131, 110543 [doi]
174. M−O Bonding Beyond the Oxo Wall: Spectroscopy and Reactivity of Cobalt(III)-Oxyl and Cobalt(III)-Oxo Complexes
Erik Andris, Rafael Navrátil, Juraj Jašík, Martin Srnec, Mònica Rodríguez, Miquel Costas, Jana Roithová
Angew. Chem. Int. Ed.​ 2019, 58, 9619-9624 [doi]
173. Highly enantioselective epoxidation of olefins by H2O2 catalyzed by a non-heme Fe(II) catalyst of a chiral tetradentate ligand
Mainak Mitra, Olaf Cussó, Satish S. Bhat, Mingzhe Sun, Marco Cianfanelli, Miquel Costas, Ebbe Nordlander
Dalton Trans.​ 2019, 48, 6123-6131 [doi]
172. Water oxidation catalysis with well-defined molecular iron complexes
Carla Casadevall, Alberto Bucci, Miquel Costas, Julio Lloret-Fillol
Adv. Inorg. Chem.​ 2019, 74, 151-196 [doi]
171. Water oxidation at base metal molecular catalysts
Julio Lloret-Fillol, Miquel Costas
Adv. Organomet. Chem.​ 2019, 71, 1-52 [doi]
170. Enantioselective Epoxidation of β,β-Disubstituted Enamides with a Manganese Catalyst and Aqueous Hydrogen Peroxide
Carlota Clarasó, Laia Vicens, Alfonso Polo, Miquel Costas
Org. Lett.​ 2019, 21, 2430-2435 [doi]
169. Characterized cis-FeV(O)(OH) intermediate mimics enzymatic oxidations in the gas phase
Margarida Borrell, Erik Andris, Rafael Navrátil, Jana Roithová, Miquel Costas
Nat. Commun.​ 2019, 10, 901 [doi]
168. Enzyme-like substrate-selectivity in C–H oxidation enabled by recognition
Giorgio Olivo, Giorgio Capocasa, Osvaldo Lanzalunga, Stefano Di Stefano, Miquel Costas
Chem. Commun.​ 2019, 55, 917-920 [doi]
167. Effective Tetradentate Compound Complexes against Leishmania spp. that Act on Critical Enzymatic Pathways of These Parasites
Kristína Urbanová, Inmaculada Ramírez-Macías, Rubén Martín-Escolano, María José Rosales, Olaf Cussó, Joan Serrano, Anna Company, Manuel Sánchez-Moreno, Miquel Costas, Xavi Ribas, Clotilde Marín
Molecules​ 2019, 24, 134 [doi]
166. Size-selective encapsulation of C60 and C60-derivatives within an adaptable naphthalene-based tetragonal prismatic supramolecular nanocapsule
Cristina García-Simón, Alba Monferrer, Marc Garcia-Borràs, Inhar Imaz, Daniel Maspoch, Miquel Costas, Xavi Ribas
Chem. Commun.​ 2019, 55, 798-801 [doi]
165. Design of Iron Coordination Complexes as Highly Active Homogenous Water Oxidation Catalysts by Deuteration of Oxidation-Sensitive Sites
Zoel Codolà, Ilaria Gamba, Ferran Acuña-Parés, Carla Casadevall, Martin Clémancey, Jean-Marc Latour, Josep M. Luis, Julio Lloret-Fillol, Miquel Costas
J. Am. Chem. Soc.​ 2019, 141, 323-333 [doi]
2018
164. Alkane Oxidation with Biologically Inspired Nonheme Iron Catalysts Based in the Triazacyclononane Ligand Scaffold
Miquel Costas
in Alkane Functionalization (Wiley, 2018) [doi]
163. Uncovering the Complexity of the Simplest Atom Transfer Reaction
Miquel Costas, Massimo Bietti
Acc. Chem. Res. 2018, 51, 2601-2602 [doi]
162. Trapping Iron(III)–Oxo Species at the Boundary of the “Oxo Wall”: Insights into the Nature of the Fe(III)–O Bond
Erik Andris, Rafael Navrátil, Juraj Jašík, Mayank Puri, Miquel Costas, Lawrence Que Jr., Jana Roithová
J. Am. Chem. Soc. 2018, 140, 14391-14400 [doi]
161. The Quest for Selectivity in Hydrogen Atom Transfer Based Aliphatic C–H Bond Oxygenation
Michela Milan, Michela Salamone, Miquel Costas, Massimo Bietti
Acc. Chem. Res. 2018, 51, 1984-1995 [doi]
160. Enantioselective aliphatic C–H bond oxidation catalyzed by bioinspired complexes
Michela Milan, Massimo Bietti, Miquel Costas
Chem. Commun. 2018, 54, 9559-9570 [doi]
159. Greening Oxidation Catalysis: Iron Catalyzed Alkene syn-Dihydroxylation with Aqueous Hydrogen Peroxide in Green Solvents
Margarida Borrell, Miquel Costas
ACS Sustainable Chem. Eng. 2018, 6, 8410-8416 [doi]
158. Aliphatic C–H Bond Oxidation with Hydrogen Peroxide Catalyzed by Manganese Complexes: Directing Selectivity through Torsional Effects
Michela Milan, Massimo Bietti, Miquel Costas
Org. Lett. 2018, 20, 2720-2723 [doi]
157. Mechanism of the Selective Fe-Catalyzed Arene Carbon–Hydrogen Bond Functionalization
Verònica Postils, Mònica Rodríguez, Gerard Sabenya, Ana Conde, M. Mar Díaz-Requejo, Pedro J. Pérez, Miquel Costas, Miquel Solà, Josep M. Luis
ACS Catal. 2018, 8, 4313-4322 [doi]
156. A Deep Cavitand Receptor Functionalized with Fe(II) and Mn(II) Aminopyridine Complexes for Bioinspired Oxidation Catalysis
Diego Vidal, Miquel Costas, Agustí Lledó
ACS Catal. 2018, 8, 3667-3672 [doi]
155. Spectroscopic and DFT Characterization of a Highly Reactive Nonheme FeV–Oxo Intermediate
Ruixi Fan, Joan Serrano-Plana, Williamson N. Oloo, Apparao Draksharapu, Estefanía Delgado-Pinar, Anna Company, Vlad Martin-Diaconescu, Margarida Borrell, Julio Lloret-Fillol, Enrique García-España, Yisong Guo, Emile L. Bominaar, Lawrence Que Jr., Miquel Costas, Eckard Münck
J. Am. Chem. Soc. 2018, 140, 3916-3928 [doi]
154. Acid-Triggered O−O Bond Heterolysis of a Nonheme FeIII(OOH) Species for the Stereospecific Hydroxylation of Strong C−H Bonds
Joan Serrano-Plana, Ferran Acuña-Parés, Valeria Dantignana, Williamson Oloo, Esther Castillo, Apparao Draksharapu, Christopher J. Whiteoak, Vlad Martin-Diaconescu, Manuel G. Basallote, Josep M. Luis, Lawrence Que Jr., Miquel Costas, Anna Company
Chem. Eur. J. 2018, 24, 5331-5340 [doi]
153. Detection of Indistinct Fe−N Stretching Bands in Iron(V) Nitrides by Photodissociation Spectroscopy
Erik Andris, Rafael Navrátil, Juraj Jašík, Gerard Sabenya, Miquel Costas, Martin Srnec, Jana Roithová
Chem. Eur. J. 2018, 24, 5078-5081 [doi]
152. Controlling Selectivity in Aliphatic C−H Oxidation through Supramolecular Recognition
Diego Vidal, Giorgio Olivo, Miquel Costas
Chem. Eur. J. 2018, 24, 5042-5054 [doi]
151. Self-Assembled Cofacial Zinc–Porphyrin Supramolecular Nanocapsules as Tuneable 1O2 Photosensitizers
Cédric Colomban, Carles Fuertes-Espinosa, Sébastien Goeb, Marc Sallé, Miquel Costas, Lluís Blancafort, Xavi Ribas
Chem. Eur. J. 2018, 24, 4371-4381 [doi]
150. Bioinspired Electro-Organocatalytic Material Efficient for Hydrogen Production
Octavio González-del Moral, Arnau Call, Federico Franco, Alicia Moya, Jose Antonio Nieto-Rodríguez, María Frías, Jose L. G. Fierro, Miquel Costas, Julio Lloret-Fillol, José Alemán, Rubén Mas-Ballesté
Chem. Eur. J. 2018, 24, 3305-3313 [doi]
149. Biologically inspired oxidation catalysis using metallopeptides
Laia Vicens, Miquel Costas
Dalton Trans. 2018, 47, 1755-1763 [doi]
148. Design of Zn-, Cu-, and Fe-Coordination Complexes Confined in a Self-Assembled Nanocage
Cédric Colomban, Vlad Martin-Diaconescu, Teodor Parella, Sébastien Goeb, Cristina García-Simón, Julio Lloret-Fillol, Miquel Costas, Xavi Ribas
Inorg. Chem. 2018, 57, 3529-3539 [doi]
147. Preparation of a coordinatively saturated μ-η2:η2-peroxodicopper(II) compound
Carla Magallón, Joan Serrano-Plana, Steven Roldán-Gómez, Xavi Ribas, Miquel Costas, Anna Company
Inorg. Chim. Acta 2018, 481, 166-170 [doi]
2017
146. Biomimetic Oxidation in Organic Synthesis
Laia Vicens, Margarida Borrell, Miquel Costas
in Science of Synthesis: Catalytic Oxidation in Organic Synthesis (Thieme, 2017) [doi]
145. Electronic and Torsional Effects on Hydrogen Atom Transfer from Aliphatic C–H Bonds: A Kinetic Evaluation via Reaction with the Cumyloxyl Radical
Michela Salamone, Teo Martin, Michela Milan, Miquel Costas, Massimo Bietti
J. Org. Chem. 2017, 82, 13542-13549 [doi]
144. Chemoselective Aliphatic C–H Bond Oxidation Enabled by Polarity Reversal
Valeria Dantignana, Michela Milan, Olaf Cussó, Anna Company, Massimo Bietti, Miquel Costas
ACS Cent. Sci. 2017, 3, 1350-1358 [doi]
143. Selective Alkane Oxidation
Anna Company, Miquel Costas
in Applied Homogeneous Catalysis with Organometallic Compounds: A Comprehensive Handbook in Four Volumes [doi]
142. Supramolecular Recognition Allows Remote, Site-Selective C−H Oxidation of Methylenic Sites in Linear Amines
Giorgio Olivo, Giulio Farinelli, Alessia Barbieri, Osvaldo Lanzalunga, Stefano Di Stefano, Miquel Costas
Angew. Chem. Int. Ed. 2017, 56, 16347-16351 [doi]
141. Spin-State-Controlled Photodissociation of Iron(III) Azide to an Iron(V) Nitride Complex
Erik Andris, Rafael Navrátil, Juraj Jašík, Gerard Sabenya, Miquel Costas, Martin Srnec, Jana Roithová
Angew. Chem. Int. Ed. 2017, 56, 14057-14060 [doi]
140. Mechanistically Driven Development of an Iron Catalyst for Selective Syn-Dihydroxylation of Alkenes with Aqueous Hydrogen Peroxide
Margarida Borrell, Miquel Costas
J. Am. Chem. Soc. 2017, 139, 12821-12829 [doi]
139. Tuning Selectivity in Aliphatic C–H Bond Oxidation of N-Alkylamides and Phthalimides Catalyzed by Manganese Complexes
Michela Milan, Giulia Carboni, Michela Salamone, Miquel Costas, Massimo Bietti
ACS Catal. 2017, 7, 5903-5911 [doi]
138. Evidence of a Sole Oxygen Atom Transfer Agent in Asymmetric Epoxidations with Fe-pdp Catalysts
Olaf Cussó, Joan Serrano-Plana, Miquel Costas
ACS Catal. 2017, 7, 5046-5053 [doi]
137. O–O Bond Activation in Cu- and Fe-Based Coordination Complexes: Breaking It Makes the Difference
Joan Serrano-Plana, Anna Company, Miquel Costas
Adv. Inorg. Chem. 2017, 70, 63-105 [doi]
136. Generation, Spectroscopic, and Chemical Characterization of an Octahedral Iron(V)-Nitrido Species with a Neutral Ligand Platform
Gerard Sabenya, Laura Lázaro, Ilaria Gamba, Vlad Martin-Diaconescu, Erik Andris, Thomas Weyhermüller, Frank Neese, Jana Roithova, Eckhard Bill, Julio Lloret-Fillol, Miquel Costas
J. Am. Chem. Soc. 2017, 139, 9168-9177 [doi]
135. Non-Heme Iron Catalysts with a Rigid Bis-Isoindoline Backbone and Their Use in Selective Aliphatic C−H Oxidation
Jianming Chen, Martin Lutz, Michela Milan, Miquel Costas, Matthias Otte, Robertus J. M. Klein Gebbink
Adv. Synth. Catal. 2017, 359, 2590-2595 [doi]
134. Nonclassical Single-State Reactivity of an Oxo-Iron(IV) Complex Confined to Triplet Pathways
Claudia Kupper, Bhaskar Mondal, Joan Serrano-Plana, Iris Klawitter, Frank Neese, Miquel Costas, Shengfa Ye, and Franc Meyer
J. Am. Chem. Soc. 2017, 139, 8939-8949 [doi]
133. A bottom up approach towards artificial oxygenases by combining iron coordination complexes and peptides
Olaf Cussó, Michael W. Giuliano, Xavi Ribas, Scott J. Miller, Miquel Costas
Chem. Sci. 2017, 8, 3660-3667 [doi]
132. Highly Enantioselective Oxidation of Nonactivated Aliphatic C–H Bonds with Hydrogen Peroxide Catalyzed by Manganese Complexes
Michela Milan, Massimo Bietti, Miquel Costas
ACS Cent. Sci.​ 2017, 3, 196-204 [doi]
131. A Copper-based Supramolecular Nanocapsule that Enables Straightforward Purification of Sc3N-based Endohedral Metallofullerene Soots
Carles Fuertes-Espinosa, Cristina García-Simón, Edison Castro, Miquel Costas, Luis Echegoyen, Xavi Ribas
Chem. Eur. J. 2017, 23, 3553-3557 [doi]
130. Chasing the Evasive Fe=O Stretch and the Spin State of the Iron(IV)–Oxo Complexes by Photodissociation Spectroscopy
Erik Andris, Rafael Navrátil, Juraj Jašík, Thibault Terencio, Martin Srnec, Miquel Costas, Jana Roithová
J. Am. Chem. Soc. 2017, 139, 2757-2765 [doi]
129. Oxidation of alkane and alkene moieties with biologically inspired nonheme iron catalysts and hydrogen peroxide: from free radicals to stereoselective transformations
Giorgio Olivo, Olaf Cussó, Margarida Borrell, Miquel Costas
J. Biol. Inorg. Chem. 2017, 22, 425-452 [doi]
128. Reversible C60 Ejection from a Metallocage through the Redox-Dependent Binding of a Competitive Guest
Cédric Colomban, György Szalóki, Magali Allain, Laura Gómez, Sébastien Goeb, Marc Sallé, Miquel Costas, Xavi Ribas
Chem. Eur. J. 2017, 23, 3016-3022 [doi]
127. Making and breaking of the O-O bond at iron complexes
Ilaria Gamba, Zoel Codolà, Julio Lloret-Fillol, Miquel Costas
Coord. Chem. Rev. 2017, 334, 2-24 [doi]
126. Catalytic C-H oxidations by nonheme mononuclear Fe(II) complexes of two pentadentate ligands: Evidence for an Fe(IV) oxo intermediate
Mainak Mitra, Hassan Nimir, David A. Hrovat, Albert A. Shteinman, Michael G. Richmond, Miquel Costas, Ebbe Nordlander
J. Molec. Catal. A: Chem. 2017, 426, 350-356 [doi]
125. Tetradentate polyamines as efficient metallodrugs for Chagas disease treatment in murine model
Francisco Olmo, Miquel Costas, Clotilde Marín, Maria José Rosales, Rubén Martín-Escolano, Olaf Cussó, Ramón Gutierrez-Sánchez, Xavi Ribas, Manuel Sánchez-Moreno
J. Chemoter. 2017, 29, 83-93 [doi]
2016
124. Biologically Inspired C−H and C=C Oxidations with Hydrogen Peroxide Catalyzed by Iron Coordination Complexes
Giorgio Olivo, Olaf Cussó, Miquel Costas
Chem. Asian J.​ 2016, 11, 3148-3158 [doi]
123. Spectroscopic, Electrochemical and Computational Characterisation of Ru Species Involved in Catalytic Water Oxidation: Evidence for a [RuV(O)(Py2Metacn)] Intermediate
Carla Casadevall, Zoel Codolà, Miquel Costas, Julio Lloret-Fillol
Chem. Eur. J. 2016, 22, 10111-10126 [doi]
122. Oxygen Atom Exchange between H2O and Non-Heme Oxoiron(IV) Complexes: Ligand Dependence and Mechanism
Maynak Puri, Anna Company, Gerard Sabenya, Miquel Costas, Lawrence Que Jr.
Inorg. Chem. 2016, 55, 5818-5827 [doi]
121. Exceedingly Fast Oxygen Atom Transfer to Olefins via a Catalytically Competent Nonheme Iron Species
Joan Serrano-Plana, Almudena Aguinaco, Raquel Belda, Enrique García-España, Manuel G. Basallote, Anna Company, Miquel Costas
Angew. Chem. Int. Ed. 2016, 55, 6310-6314 [doi]
120. Iron and Manganese Catalysts for the Selective Functionalization of Arene C(sp2)−H Bonds by Carbene Insertion
Ana Conde, Gerard Sabenya, Mònica Rodríguez, Verònica Postils, Josep M. Luis, M. Mar Díaz-Requejo, Miquel Costas, Pedro J. Pérez
Angew. Chem. Int. Ed. 2016, 55, 6530-6534 [doi]
119. Readily Accessible Bulky Iron Catalysts exhibiting Site Selectivity in the Oxidation of Steroidal Substrates
David Font, Mercè Canta, Michela Milan, Olaf Cussó, Xavi Ribas, Robertus J. M. Klein Gebbink, Miquel Costas
Angew. Chem. Int. Ed. 2016, 55, 5776-5779 [doi]
118. Delivering aminopyridine ligands into cancer cells through conjugation to the cell-penetrating peptide BP16
Marta Soler, Marta González-Bártulos, Eduard Figueras, Anna Massaguer, Lídia Feliu, Marta Planas, Xavi Ribas, Miquel Costas
Org. Biomol. Chem. 2016, 14, 4061-4070 [doi]
117. Peptide-mediated vectorization of metal complexes: conjugation strategies and biomedical applications
Marta Soler, Lídia Feliu, Marta Planas, Xavi Ribas, Miquel Costas
Dalton Trans. 2016, 45, 12970-12982 [doi]
116. Water oxidation: High five iron
Julio Lloret-Fillol, Miquel Costas
Nat. Energy 2016, 1, 16023 [doi]
115. Spectroscopic Characterization and Reactivity of Triplet and Quintet Iron(IV) Oxo Complexes in the Gas Phase
Erik Andris, Juraj Jašík, Laura Gómez, Miquel Costas, Jana Roithová
Angew. Chem. Int. Ed. 2016, 55, 3637-3642 [doi]
114. In vitro and in vivo identification of tetradentated polyamine complexes as highly efficient metallodrugs against Trypanosoma cruzi
Francisco Olmo, Olaf Cussó, Clotilde Marín, Maria José Rosales, Kristína Urbanová, R. Luise Krauth-Siegel, Miquel Costas, Xavi Ribas, Manuel Sánchez-Moreno
Exp. Parasitol. 2016, 164, 20-30 [doi]
113. Iron Catalyzed Highly Enantioselective Epoxidation of Cyclic Aliphatic Enones with Aqueous H2O2
Olaf Cussó, Marco Cianfanelli, Xavi Ribas, Robertus J. M. Klein Gebbink, Miquel Costas
J. Am. Chem. Soc. 2016, 138, 2732-2738 [doi]
112. Metallosupramolecular receptors for fullerene binding and release
Cristina García-Simón, Miquel Costas, Xavi Ribas
Chem. Soc. Rev. 2016, 45, 40-62 [doi]
2015
111. Spin States in Biochemistry and Inorganic Chemistry: Influence on Structure and Reactivity [Book]
Marcel Swart, Miquel Costas [doi]
110. Trapping a Highly Reactive Nonheme Iron Intermediate That Oxygenates Strong C–H Bonds with Stereoretention
Joan Serrano-Plana, Williamson N. Oloo, Laura Acosta-Rueda, Katlyn K. Meier, Begoña Verdejo, Enrique García-España, Manuel G. Basallote, Eckard Münck, Lawrence Que Jr., Anna Company, Miquel Costas
J. Am. Chem. Soc. 2015, 137, 15833-15842 [doi]
109. Spectroscopic Analyses on Reaction Intermediates Formed during Chlorination of Alkanes with NaOCl Catalyzed by a Nickel Complex
Apparao Draksharapu, Zoel Codolà, Laura Gómez, Julio Lloret-Fillol, Wesley R. Browne, Miquel Costas
Inorg. Chem. 2015, 54, 10656-10666 [doi]
108. Design, Preparation, and Characterization of Zn and Cu Metallopeptides Based On Tetradentate Aminopyridine Ligands Showing Enhanced DNA Cleavage Activity
Marta Soler, Eduard Figueras, Joan Serrano-Plana, Marta González-Bártulos, Anna Massaguer, Anna Company, M. Ángeles Martínez, Jaroslav Malina, Viktor Brabec, Lídia Feliu, Marta Planas, Xavi Ribas, Miquel Costas
Inorg. Chem. 2015, 54, 10542-10558 [doi]
107. Pro-Oxidant Activity of Amine-Pyridine-Based Iron Complexes Efficiently Kills Cancer and Cancer Stem-Like Cells
Marta González-Bártulos, Clara Aceves-Luquero, Jamal Qualai, Olaf Cussó, M. Ángeles Martínez, Silvia Fernández de Matos, Javier A. Menéndez, Priam Villalonga, Miquel Costas, Xavi Ribas, Anna Massaguer
PLoS One. 2015, 10, e0137800 [doi]
106. C–H Bond Oxidation Catalyzed by an Imine-Based Iron Complex: A Mechanistic Insight
Giorgio Olivo, Martina Nardi, Diego Vidal, Alessia Barbieri, Andrea Lapi, Laura Gómez, Osvaldo Lanzalunga, Miquel Costas, Stefano Di Stefano
Inorg. Chem. 2015, 54, 10141-10152 [doi]
105. H2 oxidation versus organic substrate oxidation in non-heme iron mediated reactions with H2O2
Azin Hassanpour, Ferran Acuña-Parés, Josep M. Luis, Olaf Cussó, Silvia Morales de la Rosa, José Miguel Campos-Martín, Jose L. G. Fierro, Miquel Costas, Julio Lloret-Fillol, Rubén Mas-Ballesté
Chem. Commun. 2015, 51, 14992-14995 [doi]
104. Computational Insight into the Mechanism of Alkane Hydroxylation by Non-heme Fe(PyTACN) Iron Complexes. Effects of the Substrate and Solvent
Verònica Postils, Anna Company, Miquel Solà, Miquel Costas, Josep M. Luis
Inorg. Chem. 2015, 54, 8223-8236 [doi]
103. Biologically inspired non-heme iron-catalysts for asymmetric epoxidation; design principles and perspectives
Olaf Cussó, Xavi Ribas, Miquel Costas
Chem Commun. 2015, 51, 14285-14298 [doi]
102. Structural and Reactivity Models for Copper Oxygenases: Cooperative Effects and Novel Reactivities
Joan Serrano-Plana, Isaac Garcia-Bosch, Anna Company, Miquel Costas
Acc. Chem. Res. 2015, 48, 2397-2406 [doi]
101. Nonheme Fe(IV) Oxo Complexes of Two New Pentadentate Ligands and Their Hydrogen-Atom and Oxygen-Atom Transfer Reactions
Mainak Mitra, Hassan Nimir, Serhiy Demeshko, Satish S. Bhat, Sergey O. Malinkin, Matti Haukka, Julio Lloret-Fillol, George C. Lisenky, Franc Meyer, Albert A. Shteinman, Wesley R. Browne, David A. Hrovat, Michael G. Richmond, Miquel Costas, Ebbe Nordlander
Inorg. Chem. 2015, 54, 7152-7164 [doi]
100. Identification and Spectroscopic Characterization of Nonheme Iron(III) Hypochlorite Intermediates
Apparao Draksharapu, Davide Angelone, Matthew G. Quesne, Sandeep K. Padamati, Laura Gómez, Ronald Hage, Miquel Costas, Wesley R. Browne, Sam P. de Visser
Angew. Chem. Int. Ed. 2015, 54, 4357-4361 [doi]
99. Enantioselective Hydroformylation by a Rh-Catalyst Entrapped in a Supramolecular Metallocage
Cristina García-Simón, Rafael Gramage-Doria, Saeed Raoufmoghaddam, Teodor Parella, Miquel Costas, Xavi Ribas, Joost N. H. Reek
J. Am. Chem. Soc. 2015, 137, 2680-2687 [doi]
98. Evidence for an oxygen evolving iron–oxo–cerium intermediate in iron-catalysed water oxidation
Zoel Codolà, Laura Gómez, Scott T. Kleespies, Lawrence Que Jr., Miquel Costas, Julio Lloret-Fillol
Nat. Commun. 2015, 6, 5865 [doi]
97. Synergistic Interplay of a Non-Heme Iron Catalyst and Amino Acid Coligands in H2O2 Activation for Asymmetric Epoxidation of α-Alkyl-Substituted Styrenes
Olaf Cussó, Xavi Ribas, Julio Lloret-Fillol, Miquel Costas
Angew. Chem. Int. Ed. 2015, 54, 2729-2733 [doi]
96. Recent Advances in the Selective Oxidation of Alkyl C–H Bonds Catalyzed by Iron Coordination Complexes
Mercè Canta, Mònica Rodríguez, Miquel Costas
in Site-Selective Catalysis (Springer, 2015) [doi]
95. Enzyme-triggered delivery of chlorambucil from conjugates based on the cell-penetrating peptide BP16
Marta Soler, Marta González-Bártulos, Eduard Figueras, Xavi Ribas, Miquel Costas, Anna Massaguer, Marta Planas, Lídia Feliu
Org. Biomol. Chem. 2015, 13, 1470-1480 [doi]
2014
94. Building Complexity in O2-Binding Copper Complexes. Site-Selective Metalation and Intermolecular O2-Binding at Dicopper and Heterometallic Complexes Derived from an Unsymmetric Ligand
Joan Serrano-Plana, Miquel Costas, Anna Company
Inorg. Chem. 2014, 53, 12929-12938 [doi]
93. Sponge-like molecular cage for purification of fullerenes
Cristina García-Simón, Marc Garcia-Borràs, Laura Gómez, Teodor Parella, Sílvia Osuna, Jordi Juanhuix, Inhar Imaz, Daniel Maspoch, Miquel Costas, Xavi Ribas
Nat. Commun. 2014, 5, 5557 [doi]
92. Copper-based water reduction catalysts for efficient light-driven hydrogen generation
Hernik Junge, Zoel Codolà, Anja Kammer, Nils Rockstroh, Michael Karnahl, Shu-Ping Luo, Marga-Martina Pohl, Jörg Radnik, Suresh Gatla, Sebastian Wohlrab, Julio Lloret-Fillol, Miquel Costas, Matthias Beller
J. Molec. Catal. A: Chem. 2014, 395, 449-456 [doi]
91. Structural modeling of iron halogenases: synthesis and reactivity of halide-iron(IV)-oxo compounds
Oriol Planas, Martin Clémancey, Jean-Marc Latour, Anna Company, Miquel Costas
Chem. Commun. 2014, 50, 10887-10890 [doi]
90. Direct observation of two-electron Ag(I)/Ag(III) redox cycles in coupling catalysis
Marc Font, Ferran Acuña-Parés, Teodor Parella, Jordi Serra, Josep M. Luis, Julio Lloret-Fillol, Miquel Costas, Xavi Ribas
Nat. Commun. 2014, 5, 4373 [doi]
89. Selective Ortho-Hydroxylation–Defluorination of 2-Fluorophenolates with a Bis(μ-oxo)dicopper(III) Species
Joan Serrano-Plana, Isaac Garcia-Bosch, Ryosuke Miyake, Miquel Costas, Anna Company
Angew. Chem. Int. Ed. 2014, 53, 9608-9612 [doi]
88. Theoretical Study of the Water Oxidation Mechanism with Non-heme Fe(Pytacn) Iron Complexes. Evidence That the FeIV(O)(Pytacn) Species Cannot React with the Water Molecule To Form the O–O Bond
Ferran Acuña-Parés, Miquel Costas, Josep M. Luis, Julio Lloret-Fillol
Inorg. Chem. 2014, 20, 5474-5485 [doi]
87. Unraveling the Mechanism of Water Oxidation Catalyzed by Nonheme Iron Complexes
Ferran Acuña-Parés, Zoel Codolà, Miquel Costas, Josep M. Luis, Julio Lloret-Fillol
Chem. Eur. J. 2014, 20, 5696-5707 [doi]
86. Triggering the Generation of an Iron(IV)-Oxo Compound and Its Reactivity toward Sulfides by RuII Photocatalysis
Anna Company, Gerard Sabenya, María González-Béjar, Laura Gómez, Martin Clémancey, Geneviève Blondin, Andrew J. Jasniewski, Mayank Puri, Wesley R. Browne, Jean-Marc Latour, Lawrence Que Jr., Miquel Costas, Julia Pérez-Prieto, Julio Lloret-Fillol
J. Am. Chem. Soc. 2014, 136, 4624-4633 [doi]
85. The Iron(II) Complex [Fe(CF3SO3)2(mcp)] as a Convenient, Readily Available Catalyst for the Selective Oxidation of Methylenic Sites in Alkanes
Mercè Canta, David Font, Laura Gómez, Xavi Ribas, Miquel Costas
Angew. Chem. Int. Ed. 2014, 356, 818-830 [doi]
84. Identification of BP16 as a non-toxic cell-penetrating peptide with highly efficient drug delivery properties
Marta Soler, Marta González-Bártulos, David Soriano-Castell, Xavi Ribas, Miquel Costas, Francesc Tebar, Anna Massaguer, Lídia Feliu, Marta Planas
Org. Biomol. Chem. 2014, 12, 1652-1663 [doi]
83. Fe(6-Me-PyTACN)-catalyzed, one-pot oxidative cleavage of methyl oleate and oleic acid into carboxylic acids with H2O2 and NaIO4
Peter Spannring, Irene Prat, Miquel Costas, Martin Lutz, Pieter C. A. Bruijnincx, Bert M. Weckhuysen, Robertus J. M. Klein Gebbink
Catal. Sci. Technol. 2014, 4, 708-716 [doi]
82. Evidence that steric factors modulate reactivity of tautomeric iron–oxo species in stereospecific alkane C–H hydroxylation
Mainak Mitra, Julio Lloret-Fillol, Matti Haukka, Miquel Costas, Ebbe Nordlander
Chem Commun. 2014, 50, 1408-1410 [doi]
81. Ionic liquids as reaction media in catalytic oxidations with manganese and iron pyridyl triazacyclononane complexes
Sara Lentini, Pierluca Galloni, Isaac Garcia-Bosch, Miquel Costas, Valeria Conte
Inorg. Chim. Acta 2014, 410, 60-64 [doi]
2013
80. Highly Stereoselective Epoxidation with H2O2 Catalyzed by Electron-Rich Aminopyridine Manganese Catalysts
Olaf Cussó, Isaac Garcia-Bosch, David Font, Xavi Ribas, Julio Lloret-Fillol, Miquel Costas
Org. Lett. 2013, 15, 6158-6161 [doi]
79. Asymmetric Epoxidation with H2O2 by Manipulating the Electronic Properties of Non-heme Iron Catalysts
Olaf Cussó, Isaac Garcia-Bosch, Xavi Ribas, Julio Lloret-Fillol, Miquel Costas
J. Am. Chem. Soc. 2013, 135, 14871-14878 [doi]
78. Assessing the Impact of Electronic and Steric Tuning of the Ligand in the Spin State and Catalytic Oxidation Ability of the FeII(Pytacn) Family of Complexes
Irene Prat, Anna Company, Teresa Corona, Teodor Parella, Xavi Ribas, Miquel Costas
Inorg. Chem. 2013, 52, 9229-9244 [doi]
77. Robust Iron Coordination Complexes with N-Based Neutral Ligands As Efficient Fenton-Like Catalysts at Neutral pH
Maite Canals, Rafael González-Olmos, Miquel Costas, Anna Company
Environ. Sci. Technol. 2013, 47, 9918-9927 [doi]
76. Small Molecule Models for Nonporphyrinic Iron and Manganese Oxygenases
Anna Company, Julio Lloret-Fillol, Miquel Costas
in Comprehensive Inorganic Chemistry II (El Sevier, 2013) [doi]
75. Electronic Effects on Single-Site Iron Catalysts for Water Oxidation
Zoel Codolà, Isaac Garcia-Bosch, Ferran Acuña-Parés, Irene Prat, Josep M. Luis, Miquel Costas, Julio Lloret-Fillol
Chem. Eur. J. 2013, 19, 8042-8047 [doi]
74. Highly Effective Water Oxidation Catalysis with Iridium Complexes through the Use of NaIO4
Zoel Codolà, João M. S. Cardoso, Beatriz Royo, Miquel Cosats, Julio Lloret-Fillol
Chem. Eur. J. 2013, 19, 7203-7213 [doi]
73. The Mechanism of Stereospecific C–H Oxidation by Fe(Pytacn) Complexes: Bioinspired Non-Heme Iron Catalysts Containing cis-Labile Exchangeable Sites
Irene Prat, Anna Company, Verònica Postils, Xavi Ribas, Lawrence Que Jr., Josep M. Luis, Miquel Costas
Chem. Eur. J. 2013, 19, 6724-6738 [doi]
72. Fe(PyTACN)-Catalyzed cis-Dihydroxylation of Olefins with Hydrogen Peroxide
Irene Prat, David Font, Anna Company, Kathrin Junge, Xavi Ribas, Matthias Beller, Miquel Costas
Adv. Synth. Catal. 2013, 355, 947-956 [doi]
71. Regioselective Oxidation of Nonactivated Alkyl C–H Groups Using Highly Structured Non-Heme Iron Catalysts
Laura Gómez, Mercè Canta, David Font, Irene Prat, Xavi Ribas, Miquel Costas
J. Org. Chem. 2013, 78, 1421-1433 [doi]
70. An Iron Catalyst for Oxidation of Alkyl C–H Bonds Showing Enhanced Selectivity for Methylenic Sites
Irene Prat, Laura Gómez, Mercè Canta, Xavi Ribas, Miquel Costas
Chem. Eur. J. 2013, 19, 1908-1913 [doi]
69. Spin states. Discussion of an open problem
Miquel Costas, Jeremy N. Harvey
Nat. Chem. 2013, 5, 7-9 [doi]
68. Self-Assembled Tetragonal Prismatic Molecular Cage Highly Selective for Anionic π Guests
Cristina García-Simón, Marc Garcia-Borràs, Laura Gómez, Isaac Garcia-Bosch, Sílvia Osuna, Marcel Swart, Josep M. Luis, Concepció Rovira, Manuel Almeida, Inhar Imaz, Daniel Maspoch, Miquel Costas, Xavi Ribas
Chem. Eur. J. 2013, 19, 1445-1456 [doi]
67. Nonheme oxoiron(IV) complexes of pentadentate N5 ligands: spectroscopy, electrochemistry, and oxidative reactivity
Dong Wang, Kallol Ray, Michael J. Collins, Erik R. Farquhar, Jonathan R. Frisch, Laura Gómez, Timothy A. Jackson, Marion Kerscher, Arkadius Waleska, Peter Comba, Miquel Costas, Lawrence Que Jr.
Chem. Sci. 2013, 4, 282-291 [doi]
2012
66. EPR detection of Fe(V)=O active species in nonheme iron-catalyzed oxidations
Oleg Y. Lyakin, Irene Prat, Konstantin P. Bryliakov, Miquel Costas, Evgenii P. Talsi
Catal. Commun. 2012, 29, 105-108 [doi]
65. Iron-Catalyzed C–H Hydroxylation and Olefin cis-Dihydroxylation Using a Single-Electron Oxidant and Water as the Oxygen-Atom Source
Isaac Garcia-Bosch, Zoel Codolà, Irene Prat, Xavi Ribas, Julio Lloret-Fillol, Miquel Costas
Chem. Eur. J. 2012, 18, 13269-13272 [doi]
64. Catalytic C–S, C–Se, and C–P Cross-Coupling Reactions Mediated by a CuI/CuIII Redox Cycle
Marc Font, Teodor Parella, Miquel Costas, Xavi Ribas
Organometallics 2012, 31, 7976-7982 [doi]
63. Bioinspired Oxidations Catalyzed by Nonheme Iron and Manganese Complexes
Isaac Garcia-Bosch, Irene Prat, Xavi Ribas, Miquel Costas
in Innovative Catalysis in Organic Synthesis: Oxidation, Hydrogenation, and C–X Bond Forming Reactions (Wiley, 2012) [doi]
62. Electrophilic Arene Hydroxylation and Phenol O-H Oxidations Performed by an Unsymmetric μ-η1:η1-O2-Peroxo Dicopper(II) Complex
Isaac Garcia-Bosch, Xavi Ribas, Miquel Costas
Chem. Eur. J. 2012, 18, 2113-2122 [doi]
61. Alkane C-H Oxygenation Catalyzed by Transition Metal Complexes
Anna Company, Julio Lloret, Laura Gómez, Miquel Costas
in Alkane C-H Activation by Single-Site Metal Catalysis (Springer, 2012) [doi]
60. Well-Defined Heterometallic and Unsymmetric M2O2 Complexes Arising from Binding and Activation of O2
Isaac Garcia-Bosch, Xavi Ribas, Miquel Costas
Eur. J. Org. Chem. 2012, 179-187 [doi]
59. Stereoselective Epoxidation of Alkenes with Hydrogen Peroxide using a Bipyrrolidine-Based Family of Manganese Complexes
Isaac Garcia-Bosch, Laura Gómez, Alfonso Polo, Xavi Ribas, Miquel Costas
Adv. Synth. Catal. 2012, 354, 65-70 [doi]
58. Simple and Sustainable Copper–O2 Chemistry towards High-Value Products
Miquel Costas
ChemCatChem 2012, 4, 175-176 [doi]
2011
57. Nucleophilic Aryl Fluorination and Aryl Halide Exchange Mediated by a CuI/CuIII Catalytic Cycle
Alicia Casitas, Mercè Canta, Miquel Solà, Miquel Costas, Xavi Ribas
J. Am. Chem. Soc. 2011, 133, 19385-19392 [doi]
56. Efficient water oxidation catalysts based on readily available iron coordination complexes
Julio Lloret-Fillol, Zoel Codolà, Isaac Garcia-Bosch, Laura Gómez, Juan José Pla, Miquel Costas
Nat. Chem. 2011, 3, 807-813 [doi]
55. Observation of Fe(V)=O using variable-temperature mass spectrometry and its enzyme-like C–H and C=C oxidation reactions
Irene Prat, Jennifer S. Mathieson, Mireia Güell, Xavi Ribas, Josep M. Luis, Leroy Cronin, Miquel Costas
Nat. Chem. 2011, 3, 788-793 [doi]
54. Observation and Mechanistic Study of Facile C–O Bond Formation between a Well-Defined Aryl–Copper(III) Complex and Oxygen Nucleophiles
Lauren M. Huffman, Alicia Casitas, Marc Font, Mercè Canta, Miquel Costas, Xavi Ribas, Shannon S. Stahl
Chem. Eur. J. 2011, 17, 10643-10650 [doi]
53. Bioinspired Non-heme Iron Catalysts in C-H and C=C Oxidation Reactions
Anna Company, Laura Gómez, Miquel Costas
in Iron-Containing Enzymes: Versatile Catalysts of Hydroxylation Reactions in Nature (RSC, 2011) [doi]
52. Selective C–H oxidation catalyzed by metalloporphyrins
Miquel Costas
Coord. Chem. Rev. 2011, 255, 2912-2932 [doi]
51. Aryl–O reductive elimination from reaction of well-defined aryl–CuIII species with phenolates: the importance of ligand reactivity
Alicia Casitas, Nikolaos Ioannidis, George Mitrikas, Miquel Costas, Xavi Ribas
Dalton. Trans. 2011, 40, 8796-8799 [doi]
50. Evidence for a Precursor Complex in C–H Hydrogen Atom Transfer Reactions Mediated by a Manganese(IV) Oxo Complex
Isaac Garcia-Bosch, Anna Company, Clyde W. Cady, Stenbjörn Styring, Wesley R. Browne, Xavi Ribas, Miquel Costas
Angew. Chem. Int. Ed. 2011, 50, 5648-5653 [doi]
49. A Biomimetic Iron Catalyst for the Epoxidation of Olefins with Molecular Oxygen at Room Temperature
Kristin Schröder, Benoît Join, Arlin Jose Amali, Kathrin Junge, Xavi Ribas, Miquel Costas, Matthias Beller
Angew. Chem. Int. Ed. 2011, 50, 1425-1429 [doi]
48. Modeling the cis-Oxo-Labile Binding Site Motif of Non-Heme Iron Oxygenases: Water Exchange and Oxidation Reactivity of a Non-Heme Iron(IV)-Oxo Compound Bearing a Tripodal Tetradentate Ligand
Anna Company, Irene Prat, Jonathan R. Frisch, Ruben Mas-Ballesté, Mireia Güell, Gergely Juhász, Xavi Ribas, Eckard Münck, Josep M. Luis, Lawrence Que Jr., Miquel Costas
Chem. Eur. J. 2011, 17, 1622-1634 [doi]
2010
47. Molecular mechanism of acid-triggered aryl–halide reductive elimination in well-defined aryl–CuIII–halide species
Alicia Casitas, Albert Poater, Miquel Solà, Shannon S. Stahl, Miquel Costas, Xavi Ribas
Dalton Trans. 2010, 39, 10458-10463 [doi]
46. Copper-Catalyzed Aerobic Oxidative Functionalization of an Arene C−H Bond: Evidence for an Aryl-Copper(III) Intermediate
Amanda E. King, Lauren M. Huffman, Alicia Casitas, Miquel Costas, Xavi Ribas, Shannon S. Stahl
J. Am. Chem. Soc. 2010, 132, 12068-12073 [doi]
45. Direct observation of CuI/CuIII redox steps relevant to Ullmann-type coupling reactions
Alicia Casitas, Amanda E. King, Teodor Parella, Miquel Costas, Shannon S. Stahl, Xavi Ribas
Chem. Sci. 2010, 1, 326-330 [doi]
44. O2 Activation and Selective Phenolate ortho Hydroxylation by an Unsymmetric Dicopper μ-η1:η1-Peroxido Complex
Isaac Garcia-Bosch, Anna Company, Jonathan R. Frisch, Miquel Torrent-Sucarrat, Mar Cardellach, Ilaria Gamba, Mireia Güell, Luigi Casella, Lawrence Que Jr., Xavi Ribas, Josep M. Luis, Miquel Costas
Angew. Chem. Int. Ed. 2010, 49, 2406-2409 [doi]
2009
43. Stereospecific C–H Oxidation with H2O2 Catalyzed by a Chemically Robust Site-Isolated Iron Catalyst
Laura Gómez, Isaac Garcia-Bosch, Anna Company Jordi Benet-Buchholz, Alfonso Polo, Xavier Sala, Xavi Ribas, Miquel Costas
Angew. Chem. Int. Ed. 2009, 48, 5720-5723 [doi]
42. Olefin-Dependent Discrimination between Two Nonheme HO-FeV=O Tautomeric Species in Catalytic H2O2 Epoxidations
Anna Company, Yan Feng, Mireia Güell, Xavi Ribas, Josep M. Luis, Lawrence Que Jr., Miquel Costas
Chem. Eur. J. 2009, 15, 3359-3362 [doi]
41. A Broad Substrate-Scope Method for Fast, Efficient and Selective Hydrogen Peroxide-Epoxidation
Isaac Garcia-Bosch, Xavi Ribas, Miquel Costas
Adv. Synth. Catal. 2009, 351, 348-352 [doi]
2008
40. A Novel Platform for Modeling Oxidative Catalysis in Non-Heme Iron Oxygenases with Unprecedented Efficiency
Anna Company, Laura Gómez, Xavier Fontrodona, Xavi Ribas, Miquel Costas
Chem. Eur. J. 2008, 14, 5727-5731 [doi]
39. Efficient and Selective Peracetic Acid Epoxidation Catalyzed by a Robust Manganese Catalyst
Oxo Complex
Isaac Garcia-Bosch, Anna Company, Xavier Fontrodona, Xavi Ribas, Miquel Costas
Org. Lett. 2008, 10, 2095-2098 [doi]
38. Tyrosinase-Like Reactivity in a CuIII2(μ-O)2 Species
Anna Company, Sara Palavicini, Isaac Garcia-Bosch, Ruben Mas-Ballesté, Lawrence Que Jr., Elena V. Rybak-Akimova, Luigi Casella, Xavi Ribas, Miquel Costas
Chem. Eur. J. 2008, 14, 3535-3538 [doi]
37. Nanosized trigonal prismatic and antiprismatic CuII coordination cages based on tricarboxylate linkers
Anna Company, Nans Roques, Mireia Güell, Veronica Mugnaini, Laura Gómez, Inhar Imaz, Angela Datcu, Miquel Solà, Josep M. Luis, Jaume Veciana, Xavi Ribas, Miquel Costas
Dalton. Trans. 2008, 37, 1679-1682 [doi]
2007
36. Alkane Hydroxylation by a Nonheme Iron Catalyst that Challenges the Heme Paradigm for Oxygenase Action
Anna Company, Laura Gómez, Mireia Güell, Xavi Ribas, Josep M. Luis, Lawrence Que, Miquel Costas
J. Am. Chem. Soc. 2007, 129, 15766-15767 [doi]
35. Chiral manganese complexes with pinene appended tetradentate ligands as stereoselective epoxidation catalysts
Laura Gómez, Isaac Garcia-Bosch, Anna Company, Xavier Sala, Xavier Fontrodona, Xavi Ribas, Miquel Costas
Dalton. Trans. 2007, 36, 5539-5545 [doi]
34. Structural and Kinetic Study of Reversible CO2 Fixation by Dicopper Macrocyclic Complexes. From Intramolecular Binding to Self-Assembly of Molecular Boxes
Anna Company, Joo-Eun Jee, Xavi Ribas, Josep Maria Lopez-Valbuena, Laura Gómez, Montserrat Corbella, Antoni Llobet, José Mahía, Jordi Benet-Buchholz, Miquel Costas, Rudi van Eldik
Inorg. Chem. 2007, 46, 9098-9110 [doi]
33. X-ray Absorption Spectroscopic Studies of High-Spin Nonheme (Alkylperoxo)iron(III) Intermediates
Xiaopeng Shan, Jan-Uwe Rohde, Kevin D. Koehntop, Yuming Zhou, Michael R. Bukowski, Miquel Costas, Kiyoshi Fujisawa, Lawrence Que
Inorg. Chem. 2007, 46, 8410-8417 [doi]
32. Self-assembling of nanoscopic molecular rectangles, extended helicates and porous-like materials based on macrocyclic dicopper building blocks under fine supramolecular control
Laura Gómez, Anna Company, Xavier Fontrodona, Xavi Ribas, Miquel Costas
Chem. Commun. 2007, 32, 4410-4412 [doi]
31. Fast O2 Binding at Dicopper Complexes Containing Schiff-Base Dinucleating Ligands
Anna Company, Laura Gómez, Rubén Mas-Ballesté, Ivan V. Korendovych, Xavi Ribas, Albert Poater, Teodor Parella, Xavier Fontrodona, Jordi Benet-Buchholz, Miquel Solà, Lawrence Que, Elena V. Rybak-Akimova, Miquel Costas
Inorg. Chem. 2007, 46, 4997-5012 [doi]
30. Kinetic Analysis of the Conversion of Nonheme (Alkylperoxo)iron(III) Species to Iron(IV) Complexes
Michael P. Jensen, Antoni Mairata i Payeras, Adam T. Fiedler, Miquel Costas, József Kaizer, Audria Stubna, Eckard Münck, Lawrence Que
Inorg. Chem. 2007, 46, 2398-2408 [doi]
2006
29. Redox-Controlled Molecular Flipper Based on a Chiral Cu Complex
Anna Company, Mireia Güell, Dana Popa, Jordi Benet-Buchholz, Teodor Parella, Xavier Fontrodona, Antoni Llobet, Miquel Solà, Xavi Ribas, Josep M. Luis, Miquel Costas
Inorg. Chem. 2006, 45, 9643-9645 [doi]
28. Ligand Topology Effects on Olefin Oxidations by Bio-Inspired [FeII(N2Py2)] Catalyst
Rubén Mas-Ballesté, Miquel Costas, Tieme van den Berg, Lawrence Que Jr.
Chem. Eur. J. 2006, 12, 7489-7500 [doi]
27. O2 Chemistry of Dicopper Complexes with Alkyltriamine Ligands. Comparing Synergistic Effects on O2 Binding
Anna Company, Diana Lamata, Albert Poater, Miquel Solà, Elena V. Rybak-Akimova, Lawrence Que, Xavier Fontrodona, Teodor Parella, Antoni Llobet, Miquel Costas
Inorg. Chem. 2006, 45, 5239-5241 [doi]
26. Copper(II) Hexaaza Macrocyclic Binuclear Complexes Obtained from the Reaction of Their Copper(I) Derivates and Molecular Dioxygen
Miquel Costas, Xavi Ribas, Albert Poater, Josep Maria López Valbuena, Raül Xifra, Anna Company, Miquel Duran, Miquel Solà, Antoni Llobet, Montserrat Corbella, Miguel Angel Usón, José Mahía, Xavier Solans, Xiaopeng Shan, Jordi Benet-Buchholz
Inorg. Chem. 2006, 45, 3569-3581 [doi]
25. Oxoiron(IV) complexes of the tris(2-pyridylmethyl)amine ligand family: effect of pyridine α-substituents
Tapan K. Paine, Miquel Costas, József Kaizer, Lawrence Que Jr.
J. Biol. Inorg. Chem. 2006, 11, 272-276 [doi]
24. Isomeric Molecular Rectangles Resulting from Self-Assembly of Dicopper Complexes of Macrocyclic Ligands
Anna Company, Laura Gómez, Josep Maria López Valbuena, Ruben Mas-Ballesté, Jordi Benet-Buchholz, Antoni Llobet, Miquel Costas
Inorg. Chem. 2006, 45, 2501-2508 [doi]
1997 - 2005
23. High-Valent Nonheme Iron. Two Distinct Iron(IV) Species Derived from a Common Iron(II) Precursor
Michael P. Jensen, Miquel Costas, Raymond Y. N. Ho, József Kaizer, Antoni Mairata i Payeras, Eckard Münck, Lawrence Que, Jan-Uwe Rohde, Audria Stubna
J. Am. Chem. Soc. 2005, 127, 10512-10525 [doi]
22. XAS characterization of end-on and side-on peroxoiron(III) complexes of the neutral pentadentate N-donor ligand N-methyl-N,N′,N′-tris(2-pyridylmethyl)ethane-1,2-diamine
Kevin D. Koehntop, Jan-Uwe Rohde, Miquel Costas, Lawrence Que Jr.
Dalton Trans. 2004, 33, 3191-3198 [doi]
21. A Structural and Mössbauer Study of Complexes with Fe2(μ-O(H))2 Cores: Stepwise Oxidation from FeII(μ–OH)2FeII through FeII(μ–OH)2FeIII to FeIII(μ–O)(μ–OH)FeIII
Audria Stubna, Du-Hwan Jo, Miquel Costas, William W. Brenessel, Hanspeter Andres, Emile L. Bominaar, Eckard Münck, Lawrence Que
Inorg. Chem. 2004, 43, 3067-3079 [doi]
20. Synthesis, Structure and Hydrolytic Properties of a Family of New Zn Complexes Containing Hexaazamacrocyclic Ligands
Miquel Costas, Carmen Anda, Antoni Llobet, Teodor Parella, Helen Stoeckli Evans, Elena Pinilla
Eur. J. Inorg. Chem. 2004, 857-865 [doi]
19. Dioxygen Activation at Mononuclear Nonheme Iron Active Sites: Enzymes, Models, and Intermediates
Miquel Costas, Mark P. Mehn, Michael P. Jensen, Lawrence Que
Chem. Rev. 2004, 104, 939-986 [doi]
18. Role of Carboxylate Bridges in Modulating Nonheme Diiron(II)/O2 Reactivity
Miquel Costas, Clyde W. Cady, Sergey V. Kryatov, Manabendra Ray, Meghan J. Ryan, Elena V. Rybak-Akimova, Lawrence Que
Inorg. Chem. 2003, 42, 7519-7530 [doi]
17. A Dramatic Push Effect on the Homolysis of FeIII(OOR) Intermediates To Form Non-Heme FeIV=O Complexes
József Kaizer, Miquel Costas, Lawrence Que Jr.
Angew. Chem. Int. Ed. 2003, 42, 3671-3673 [doi]
16. Iron-Catalyzed Olefin cis-Dihydroxylation by H2O2: Electrophilic versus Nucleophilic Mechanisms
Megumi Fujita, Miquel Costas, Lawrence Que
J. Am. Chem. Soc. 2003, 125, 9912-9913 [doi]
15. Dinuclear Copper(I) Complexes with Hexaaza Macrocyclic Dinucleating Ligands: Structure and Dynamic Properties
Miquel Costas, Raul Xifra, Antoni Llobet, Miquel Solà, Juvencio Robles, Teodor Parella, Helen Stoeckli-Evans, Markus Neuburger
Inorg. Chem. 2003, 42, 4456-4468 [doi]
14. An FeIV=O complex of a tetradentate tripodal nonheme ligand
Mi Hee Lim, Jan-Uwe Rohde, Audria Stubna, Michael R. Bukowski, Miquel Costas, Raymond Y. N. Ho, Eckard Münck, Wonwoo Nam, Lawrence Que, Jr.
Proc. Nat. Am. Sci. 2003, 100, 3665-3670 [doi]
13. Copper(I)−Dioxygen Reactivity of [(L)CuI]+ (L = Tris(2-pyridylmethyl)amine): Kinetic/Thermodynamic and Spectroscopic Studies Concerning the Formation of Cu−O2and Cu2−O2 Adducts as a Function of Solvent Medium and 4-Pyridyl Ligand Substituent Variations
Christiana Xin Zhang, Susan Kaderli, Miquel Costas, Eun-il Kim, Yorck-Michael Neuhold, Kenneth D. Karlin, Andreas D. Zuberbühler
Inorg. Chem. 2003, 42, 1807-1824 [doi]
12. 4-Nitrocatechol as a probe of a Mn(II)-dependent extradiol-cleaving catechol dioxygenase (MndD): comparison with relevant Fe(II) and Mn(II) model complexes
Mark F. Reynolds, Miquel Costas, Masami Ito, Du-Hwan Jo, Alex A. Tipton, Adam K. Whiting, Lawrence Que
J. Biol. Inorg. Chem. 2003, 8, 263-272 [doi]
11. Ligand Topology Tuning of Iron-Catalyzed Hydrocarbon Oxidations
Miquel Costas, Lawrence Que Jr.
Angew. Chem. Int. Ed. 2002, 41, 2179-2181 [doi]
10. High conversion of olefins to cis-diols by non-heme iron catalysts and H2O2
Ju Yeon Ryu, Jinheung Kim, Miquel Costas, Kui Chen, Wonwoo Nam, Lawrence Que Jr.
Chem. Commun. 2002, 27, 1288-1289 [doi]
9. Olefin Cis-Dihydroxylation versus Epoxidation by Non-Heme Iron Catalysts: Two Faces of an FeIII−OOH Coin
Kui Chen, Miquel Costas, Jinheung Kim, Adrianne K. Tipton, Lawrence Que
J. Am. Chem. Soc. 2002, 124, 3026-3035 [doi]
8. Spin state tuning of non-heme iron-catalyzed hydrocarbon oxidations: participation of FeIII–OOH and FeVO intermediates
Kui Chen, Miquel Costas, Lawrence Que Jr.
J. Chem. Soc., Dalton Trans. 2002, 672-679 [doi]
7. A Synthetic Model for the Putative FeIV2O2 Diamond Core of Methane Monooxygenase Intermediate Q
Miquel Costas, Jan-Uwe Rohde, Audria Stubna, Raymond Y. N. Ho, Luca Quaroni, Eckard Münck, Lawrence Que
J. Am. Chem. Soc. 2001, 123, 12931-12932 [doi]
6. Modeling Rieske Dioxygenases: The First Example of Iron-Catalyzed Asymmetric cis-Dihydroxylation of Olefins
Miquel Costas, Adrianne K. Tipton, Kui Che, Du-Hwan Jo, Lawrence Que
J. Am. Chem. Soc. 2001, 123, 6722-6723 [doi]
5. A nonheme iron(II) complex that models the redox cycle of lipoxygenase
Jinheung Kim, Yan Zang, Miquel Costas, Roger G. Harrison, Elizabeth C. Wilkinson, Lawrence Que Jr.
J. Biol. Inorg. Chem. 2001, 6, 275-284 [doi]
4. Biomimetic nonheme iron catalysts for alkane hydroxylation
Miquel Costas, Kui Chen, Lawrence Que Jr.
Coord. Chem. Rev. 2000, 200-202, 517-544 [doi]
3. FeCl2py4+ catalyzed transformation of aromatic amines by HOOH under mild conditions
Miquel Costas, Isabel Romero, M. Ángeles Martínez, Antoni Llobet, Donald T. Sawyer, Josep Caixach
J. Molec. Catal. A: Chem. 1999, 148, 49-58 [doi]
2. Copper(I)-induced activation of dioxygen for the oxidation of organic substrates under mild conditions. An evaluation of ligand effects
Miquel Costas, Antoni Llobet
J. Molec. Catal. A: Chem. 1999, 142, 113-124 [doi]
1. The functionalization of saturated hydrocarbons. Part 39. Further evidence for the role of the iron-carbon bond in Gif chemistry
Derek H. R. Barton, Miquel Costas, John MacKinnon
Tetrahedron 1997, 53, 7417-4728 [doi]
